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Quora for JEE Mains and NEET: Study Rate Community

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  1. Asked: March 10, 2024In: JEE Mains

    If the electron revolving in the 3rd Bohr’s orbit of Hydrogen species has a radius is R. Then what will be its radius in the 4th orbit in terms of R?

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 10, 2024 at 2:54 pm

    To find the radius of the electron in the 4th Bohr's orbit of hydrogen in terms of \( R \), the radius in the 3rd orbit, we can use the relation of radii of Bohr's orbits: \[ R_n = \frac{n^2}{Z} R \] where: - \( R_n \) is the radius of the nth orbit, - \( n \) is the principal quantum number, - \( ZRead more

    To find the radius of the electron in the 4th Bohr’s orbit of hydrogen in terms of \( R \), the radius in the 3rd orbit, we can use the relation of radii of Bohr’s orbits:

    \[ R_n = \frac{n^2}{Z} R \]

    where:
    – \( R_n \) is the radius of the nth orbit,
    – \( n \) is the principal quantum number,
    – \( Z \) is the atomic number (for hydrogen, \( Z = 1 \)),
    – \( R \) is the radius in the first orbit.

    Given that the electron is initially in the 3rd orbit (\( n = 3 \)), we have:

    \[ R_3 = \frac{3^2}{1} R = 9R \]

    Now, to find the radius in the 4th orbit (\( n = 4 \)), we use the same formula:

    \[ R_4 = \frac{4^2}{1} R = 16R \]

    Therefore, the radius of the electron in the 4th orbit in terms of \( R \) is \( 16R \), which corresponds to option 2) \( \left(\frac{16}{9}\right)R \).

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  2. Asked: March 10, 2024In: JEE Mains

    Which of the following compounds have colour due to d-d transition?

    Bharti
    Best Answer
    Bharti Beginner
    Added an answer on March 10, 2024 at 2:52 pm

    Compounds that exhibit color due to d-d transitions typically contain transition metal ions with partially filled d orbitals. A. KMnO4: Potassium permanganate (KMnO4) is a strong oxidizing agent and does not exhibit color due to d-d transitions. Its color is due to charge transfer transitions. B. K2Read more

    Compounds that exhibit color due to d-d transitions typically contain transition metal ions with partially filled d orbitals.

    A. KMnO4: Potassium permanganate (KMnO4) is a strong oxidizing agent and does not exhibit color due to d-d transitions. Its color is due to charge transfer transitions.

    B. K2Cr2O7: Potassium dichromate (K2Cr2O7) is orange-red in color due to d-d transitions in the chromium (Cr) ions. The Cr(VI) ions in the compound have partially filled d orbitals, which absorb light in the visible region, resulting in the observed color.

    C. K2CrO4: Potassium chromate (K2CrO4) is yellow in color due to charge transfer transitions. It does not exhibit d-d transitions.

    D. CuSO4.5H2O: Copper(II) sulfate pentahydrate (CuSO4.5H2O) is blue in color due to d-d transitions in the copper (Cu) ions. The Cu(II) ions in the compound have partially filled d orbitals, which absorb light in the visible region, resulting in the observed blue color.

    Therefore, the compounds that have color due to d-d transitions are options (B) K2Cr2O7 and (D) CuSO4.5H2O.

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  3. Asked: March 10, 2024In: JEE Mains

    Which of the following options contain amphoteric oxide(s) only?

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 10, 2024 at 2:50 pm

    Amphoteric oxides are compounds that can act as both acidic and basic oxides, depending on the conditions. They can react with both acids and bases to form salts and water. i. SnO2 and SiO: Both tin(IV) oxide (SnO2) and silicon monoxide (SiO) are amphoteric oxides. They can react with both acids andRead more

    Amphoteric oxides are compounds that can act as both acidic and basic oxides, depending on the conditions. They can react with both acids and bases to form salts and water.

    i. SnO2 and SiO: Both tin(IV) oxide (SnO2) and silicon monoxide (SiO) are amphoteric oxides. They can react with both acids and bases.

    ii. SiO2: Silicon dioxide (SiO2) is not an amphoteric oxide. It is primarily acidic in nature and does not exhibit amphoteric properties.

    iii. SnO2 and PbO2: Tin(IV) oxide (SnO2) is amphoteric, but lead dioxide (PbO2) is not amphoteric. It primarily exhibits acidic properties.

    iv. CO and SiO: Carbon monoxide (CO) is not an amphoteric oxide. It is primarily considered a neutral oxide. Silicon monoxide (SiO) is amphoteric.

    Therefore, the correct option containing only amphoteric oxides is (i) SnO2 and SiO.

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  4. Asked: March 10, 2024In: JEE Mains

    On which of the following factors does the electrical conductivity of an electrolytic cell does not depend?

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 10, 2024 at 2:48 pm

    The electrical conductivity of an electrolytic cell depends on various factors, including: i. Concentration of electrolyte: The conductivity of an electrolytic solution generally increases with an increase in the concentration of the electrolyte. This is because a higher concentration of ions allowsRead more

    The electrical conductivity of an electrolytic cell depends on various factors, including:

    i. Concentration of electrolyte: The conductivity of an electrolytic solution generally increases with an increase in the concentration of the electrolyte. This is because a higher concentration of ions allows for more charge carriers, leading to increased conductivity.

    ii. Amount of electrolyte added: Similar to concentration, adding more electrolyte to a solution increases the number of ions present and therefore increases the conductivity.

    iii. Temperature: Generally, the conductivity of electrolytic solutions increases with an increase in temperature. This is because higher temperatures lead to increased ion mobility, allowing ions to move more freely and increasing conductivity.

    iv. Nature of electrode: The nature of the electrode can affect the conductivity of an electrolytic cell to some extent. For example, certain electrode materials may have a higher resistance, which can affect the overall conductivity of the cell.

    Out of the given options, the electrical conductivity of an electrolytic cell does not depend on the nature of the electrode (iv). While the nature of the electrode may have some influence, it is not a primary factor affecting conductivity compared to the other factors listed.

    Therefore, the correct answer is (iv) Nature of electrode.

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  5. Asked: March 10, 2024In: JEE Mains

    Which of the following compounds is white in colour?

    Parul Singla
    Best Answer
    Parul Singla Teacher
    Added an answer on March 10, 2024 at 2:46 pm

    The color of a compound is often determined by the transition metal ion present in it and the oxidation state of that metal ion. i. ZnSO4: Zinc sulfate is a white compound. Zinc ions (Zn^2+) typically do not exhibit any color in solution. ii. CuSO4: Copper sulfate is blue in color. Copper ions (Cu^2Read more

    The color of a compound is often determined by the transition metal ion present in it and the oxidation state of that metal ion.

    i. ZnSO4: Zinc sulfate is a white compound. Zinc ions (Zn^2+) typically do not exhibit any color in solution.

    ii. CuSO4: Copper sulfate is blue in color. Copper ions (Cu^2+) in solution often exhibit a blue color due to the presence of partially filled d orbitals.

    iii. FeSO4: Iron(II) sulfate is pale green in color. Iron(II) ions (Fe^2+) typically give a green color to solutions due to the presence of partially filled d orbitals.

    iv. FeCl3: Iron(III) chloride is yellow-brown in color. Iron(III) ions (Fe^3+) often exhibit a yellow or brown color in solution.

    Therefore, among the given options, only (i) ZnSO4 is white in color.

    So, the correct answer is (i) ZnSO4.

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  6. Asked: March 10, 2024In: JEE Mains

    In a simple pendulum of length 10 m, the string is initially kept horizontal and the bob is released. 10% of energy is lost till the bob reaches the lowermost position.

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 10, 2024 at 2:44 pm

    Let's denote the initial potential energy of the bob as \( PE_i \) and the final potential energy at the lowermost position as \( PE_f \). Similarly, let's denote the initial kinetic energy as \( KE_i \) and the final kinetic energy at the lowermost position as \( KE_f \). Since the pendulum bob isRead more

    Let’s denote the initial potential energy of the bob as \( PE_i \) and the final potential energy at the lowermost position as \( PE_f \). Similarly, let’s denote the initial kinetic energy as \( KE_i \) and the final kinetic energy at the lowermost position as \( KE_f \).

    Since the pendulum bob is initially at rest when the string is horizontal, its initial kinetic energy (\( KE_i \)) is zero.

    The potential energy of the bob at the initial position (\( PE_i \)) is fully converted to kinetic energy at the lowermost position, assuming no energy loss. Therefore, at the lowermost position, the kinetic energy (\( KE_f \)) equals the potential energy at the initial position (\( PE_i \)).

    Given that 10% of the energy is lost, the final potential energy (\( PE_f \)) is 90% of the initial potential energy (\( PE_i \)).

    Using the conservation of mechanical energy, we have:

    \[ PE_i – PE_f = KE_f – KE_i \]

    Since \( KE_i = 0 \), this simplifies to:

    \[ PE_i – PE_f = KE_f \]

    \[ PE_i – 0.9PE_i = KE_f \]

    \[ 0.1PE_i = KE_f \]

    Now, the potential energy of a pendulum bob at a height \( h \) is given by:

    \[ PE = mgh \]

    Given that the length of the pendulum is \( 10 \) m, at the lowermost position, \( h = 10 \) m. Therefore, the initial potential energy (\( PE_i \)) is:

    \[ PE_i = mgh = mg(10) \]

    Since the mass (\( m \)) of the pendulum bob cancels out when calculating the speed, we can ignore it.

    Now, we can calculate \( KE_f \):

    \[ KE_f = 0.1PE_i = 0.1 \times mg \times 10 \]

    \[ KE_f = 1 \times g \times 10 \]

    \[ KE_f = 10g \]

    Now, at the lowermost position, all of the potential energy is converted into kinetic energy, so:

    \[ KE_f = \frac{1}{2}mv^2 \]

    \[ 10g = \frac{1}{2}v^2 \]

    \[ v^2 = 20g \]

    \[ v = \sqrt{20g} \]

    Given that \( g = 9.8 \, \text{m/s}^2 \) (approximately), we can calculate \( v \):

    \[ v = \sqrt{20 \times 9.8} \]

    \[ v \approx \sqrt{196} \]

    \[ v \approx 14 \, \text{m/s} \]

    However, this speed represents the magnitude of the velocity vector. Since the bob is moving vertically downward, the speed is positive.

    Therefore, the correct option is (C) \( 7\sqrt{5} \, \text{m/s} \).

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  7. Asked: March 8, 2024In: JEE Mains

    Calculate the temperature (in K) at which kinetic energy of mono atomic gaseous molecule is equal to 0.414 ev

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 8, 2024 at 4:46 pm

    The kinetic energy (\( KE \)) of a monoatomic gaseous molecule can be calculated using the formula: \[ KE = \frac{3}{2} kT \] where: \( k \) is the Boltzmann constant (\( 1.38 \times 10^{-23} \, \text{J/K} \)), \( T \) is the temperature in Kelvin. Given that the kinetic energy is \( 0.414 \, \text{Read more

    The kinetic energy (\( KE \)) of a monoatomic gaseous molecule can be calculated using the formula:

    \[ KE = \frac{3}{2} kT \]

    where:
    \( k \) is the Boltzmann constant (\( 1.38 \times 10^{-23} \, \text{J/K} \)),
    \( T \) is the temperature in Kelvin.

    Given that the kinetic energy is \( 0.414 \, \text{eV} \), we need to convert it to joules since the Boltzmann constant is in joules:

    \[ 1 \, \text{eV} = 1.602 \times 10^{-19} \, \text{J} \]

    So, \( 0.414 \, \text{eV} = 0.414 \times 1.602 \times 10^{-19} \, \text{J} \)

    \[ = 6.627 \times 10^{-20} \, \text{J} \]

    Now, we can set up the equation:

    \[ 6.627 \times 10^{-20} \, \text{J} = \frac{3}{2} \times (1.38 \times 10^{-23} \, \text{J/K}) \times T \]

    Solving for \( T \):

    \[ T = \frac{6.627 \times 10^{-20}}{\frac{3}{2} \times 1.38 \times 10^{-23}} \]

    \[ T \approx 3198 \, \text{K} \]

    Therefore, the temperature at which the kinetic energy of the monoatomic gaseous molecule is equal to \(0.414 \, \text{eV}\) is approximately \(3198 \, \text{K}\).

    So, the correct option is (a) \(3198 \, \text{K}\).

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  8. Asked: March 8, 2024In: JEE Mains

    During SN1 reaction which of the following statement is correct?

    Nitya
    Nitya Pundit
    Added an answer on March 8, 2024 at 4:45 pm

    During an SN1 (Substitution Nucleophilic Unimolecular) reaction, the leaving group departs first, forming a carbocation intermediate. In the subsequent step, the nucleophile attacks the carbocation to form the product. Since the nucleophile attacks the carbocation from either side with equal probabiRead more

    During an SN1 (Substitution Nucleophilic Unimolecular) reaction, the leaving group departs first, forming a carbocation intermediate. In the subsequent step, the nucleophile attacks the carbocation to form the product.

    Since the nucleophile attacks the carbocation from either side with equal probability, SN1 reactions typically result in a mixture of both retention and inversion products. This phenomenon is known as racemization.

    Therefore, the correct answer is option (c) Almost racemization.

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  9. Asked: March 8, 2024In: JEE Mains

    Which type of linkage is present in nucleotide between base and sugar?

    Bharti
    Best Answer
    Bharti Beginner
    Added an answer on March 8, 2024 at 4:43 pm

    The linkage present in a nucleotide between the base and sugar is known as a glycosidic linkage. Therefore, the correct answer is option (b) Glycosidic linkage.

    The linkage present in a nucleotide between the base and sugar is known as a glycosidic linkage.

    Therefore, the correct answer is option (b) Glycosidic linkage.

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  10. Asked: March 8, 2024In: JEE Mains

    Ethanol shows turbidity with lucas reagent (conc. HCl + anhydrous ZnCl2)?

    Nitya
    Best Answer
    Nitya Pundit
    Added an answer on March 8, 2024 at 4:41 pm
    This answer was edited.

    Ethanol reacts with Lucas reagent (conc. HCl + anhydrous ZnCl2) to form a cloudy or turbid solution due to the formation of an alkyl chloride. The reaction occurs as follows: \[ \text{CH}_3\text{CH}_2\text{OH} + \text{HCl} \xrightarrow{} \text{CH}_3\text{CH}_2\text{Cl} + \text{H}_2\text{O} \] This rRead more

    Ethanol reacts with Lucas reagent (conc. HCl + anhydrous ZnCl2) to form a cloudy or turbid solution due to the formation of an alkyl chloride.

    The reaction occurs as follows:

    \[ \text{CH}_3\text{CH}_2\text{OH} + \text{HCl} \xrightarrow{} \text{CH}_3\text{CH}_2\text{Cl} + \text{H}_2\text{O} \]

    This reaction is a typical test for the presence of a primary or secondary alcohol. Primary alcohols react slowly with Lucas reagent and may not produce a turbid solution immediately. However, secondary alcohols react more readily and form turbidity faster.

    Therefore, the correct answer is likely option (b) After 5 to 7 mins, as this timeframe is typical for the turbidity to become apparent with ethanol.

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