Here we will provide you the 50+ MCQ Questions of Coordination Compounds for NEET-UG. Surface Chemistry is the chapter 7 in Class XII or Class 12 Chemistry NCERT Unit Coordination Compounds NEET (conducted by NTA) is based on the NCERT book.
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Coordination Compounds NEET MCQ
Which of the following is a monodentate ligand?
(A) NH3
(B) H2O
(C) CO
(D) CN-
The oxidation state of Co in K[Co(CN)6] is:
(A) +4
(B) +2
(C) +1
(D) -1
Complexes that do not contain any unpaired electrons are known as:
(A) high-spin complexes
(B) low-spin complexes
(C) spin-free complexes
(D) none of the above
The number of isomers possible for the complex [Co(en)(NH3)Cl2]+ are:
(A) 1
(B) 2
(C) 3
(D) 4
Which of the following is an example of bidentate ligand?
(A) H2O
(B) NH3
(C) C2O4(2-)
(D) Cl-
The IUPAC name of the complex ion [Cr(CN)6]3- is:
(A) hexacyanochromite(III) ion
(B) tricyanochromium(III) ion
(C) hexacyanochromate(III) ion
(D) tricyanochromite(III) ion
The coordination number of the central metal atom in a square planar complex is:
(A) 4
(B) 5
(C) 6
(D) 7
Which of the following is an example of a chelating agent?
(A) NH3
(B) CO
(C) EDTA
(D) Cl-
The geometry of the complex [Cu(NH3)4]2+ is:
(A) tetrahedral
(B) square planar
(C) octahedral
(D) trigonal bipyramidal
Which among the following forms a dative covalent bond in a coordination compound?
(A) Ligand
(B) Central metal atom
(C) Both ligand and central atom form dative covalent bond
(D) Neither ligand nor central atom form dative covalent bond.
The magnetic moment of the complex ion [Fe(H2O)6]2+ is:
(A) 4.7 BM
(B) 1.7 BM
(C) 5.9 BM
(D) 0 BM
The number of geometrical isomers possible for [Co(en)2Cl2]+ are
(a) 0
(b) 1
(c) 2
(d) 3
Which of the following complexes will have the highest spin-only magnetic moment value?
(a) [Co(H2O)6]3+
(b) [Co(H2O)6]2+
(c) [Co(NH3)6]3+
(d) [Co(NH3)6]2+
Which of the following is NOT a chelating ligand?
(a) EDTA
(b) CN−
(c) C2O42−
(d) NH3
The IUPAC name of [Cr(NH3)3Cl3] is
(a) triamminetrichlorochromium(III)
(b) triamminetricarbonatochromium(III)
(c) triamminetrichlorochromium(IV)
(d) triamminetricarbonatochromium(IV)
The number of isomers possible for [Co(NH3)4Br2]+ are
(a) 2
(b) 3
(c) 4
(d) 6
Which of the following complex ions is NOT expected to exhibit geometrical isomerism?
(a) [Co(en)2(H2O)2]2+
(b) [Co(en)3]3+
(c) [Co(NH3)4Cl2]+
(d) [Co(en)2Cl2]+
Which of the following is NOT a coordination entity?
(a) [Fe(CN)6]3−
(b) [Fe(CN)6]4−
(c) [Fe(H2O)6]2+
(d) [Fe(H2O)6]3+
The IUPAC name of [Co(NH3)5SO4]Br is
(a) pentaamminesulphatocobalt(II) bromide
(b) pentaamminesulphatocobalt(III) bromide
(c) pentaamminesulphato-N-coabalt(II) bromide
(d) pentaamminesulphato-N-coabalt(III) bromide
Which of the following is NOT a coordination number?
(a) 4
(b) 5
(c) 8
(d) 9
Which of the following compounds is expected to have the highest value of magnetic moment?
(a) [Cr(NH3)6]Cl3
(b) [Cr(NH3)6]Cl2
(c) [Cr(en)3]Cl3
(d) [Cr(CN)6]3−
Which of the following is not a bidentate ligand?
a. Ethylenediammine
b. Glycinate
c. Oxalate
d. Cyanide
The metal which exhibits highest oxidation state in Group 15 is:
a. Nitrogen
b. Phosphorus
c. Arsenic
d. Bismuth
Which of the following statements is correct for [Co(NH3)6]3+ complex ion?
a. It is diamagnetic
b. It has a magnetic moment corresponding to three unpaired electrons
c. It shows geometrical isomerism
d. It can show optical isomerism
Which of the following complexes will show zero crystal field stabilization energy (CFSE)?
a. d5 complex
b. d8 complex
c. d9 complex
d. d10 complex
Answer: c
Which of the following statements is correct for the complex [Co(NH3)4(CN)2]+?
a. It is a square planar complex with sp^3d^2 hybridization
b. It shows linkage isomerism
c. The CN ligands act as ambidentate ligands
d. Both b and c
Which of the following is not used as a test to distinguish between Fe2+ and Fe3+ ions in solution?
a. Potassium ferrocyanide test
b. Prussian blue test
c. Chromyl chloride test
d. Thiocyanate test
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