50+ JEE Mains MCQ Questions Thermodynamics with Solutions

Preparing for the Joint Entrance Exam (JEE) can be a daunting task. With so many subjects to cover and so many topics to study, it can be challenging to know where to start. One essential topic in the JEE Mains syllabus is the Thermodynamics. In this article, we will provide 50+ MCQ questions on the Thermodynamics, along with detailed solutions to help you prepare for the JEE Mains exam.

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These 50+ MCQ questions are selected by the experts of studyrate.in and these are more difficult questions, which will help you to better understand Thermodynamics JEE Mains MCQ Questions with Answers.

Thermodynamics JEE Mains MCQ


Which of the following statements is true regarding the first law of thermodynamics?
A) Energy is neither created nor destroyed.
B) Energy flows from a lower temperature to a higher temperature.
C) The entropy of a system always decreases.
D) The internal energy of a system is constant.

Answer: A Explanation: The first law of thermodynamics, also known as the law of conservation of energy, states that energy cannot be created or destroyed in an isolated system. It can only be transferred or converted from one form to another.

Which of the following processes is endothermic?
A) Freezing of water
B) Combustion of gasoline
C) Condensation of steam
D) Dissolution of salt in water

Answer: B Explanation: Endothermic processes absorb heat from the surroundings, and the combustion of gasoline is an example of an endothermic process as it requires the input of heat energy.

The standard enthalpy of formation of an element in its most stable form is:
A) Zero
B) Positive
C) Negative
D) Cannot be determined

Answer: A Explanation: The standard enthalpy of formation of an element in its most stable form is defined as zero. It serves as a reference point for measuring the enthalpy changes of other substances.

The value of ΔG° for a spontaneous reaction is:
A) Positive
B) Negative
C) Zero
D) Cannot be determined

Answer: B Explanation: For a spontaneous reaction, the value of ΔG° (standard Gibbs free energy change) is negative, indicating that the reaction will proceed in the forward direction without any external intervention.

The entropy of a system is a measure of:
A) Energy content
B) Disorder
C) Temperature
D) Pressure

Answer: B Explanation: The entropy of a system is a measure of the disorder or randomness of its particles. A system with higher entropy has greater disorder.

Which of the following processes is accompanied by a decrease in entropy?
A) Melting of ice
B) Evaporation of water
C) Mixing of two gases
D) Condensation of steam

Answer: D Explanation: Condensation of steam is accompanied by a decrease in entropy as the water vapor molecules become more ordered and organized in the liquid state.

The standard enthalpy change of a reaction can be determined using:
A) Hess’s law
B) Kirchhoff’s law
C) Le Chatelier’s principle
D) Avogadro’s law

Answer: A Explanation: Hess’s law states that the standard enthalpy change of a reaction is the sum of the standard enthalpy changes of the individual steps of the reaction. It allows us to calculate the enthalpy change for a reaction indirectly by using known enthalpy changes of other reactions.

The thermodynamic state function that accounts for the randomness or disorder of a system is:
A) Enthalpy
B) Entropy
C) Internal energy
D) Gibb’s free energy

Answer: B Explanation: Entropy is the thermodynamic state function that accounts for the randomness or disorder of a system. It quantifies the number of microstates available to a system at a given macroscopic state.

The enthalpy change for a chemical reaction can be determined experimentally using:
A) Calorimetry
B) Spectroscopy
C) Chromatography
D) Gravimetry

Answer: A Explanation: Calorimetry is a technique used to measure the heat flow in a chemical reaction. By measuring the temperature change in a calorimeter, the enthalpy change can be determined.

Which of the following is an extensive property of a system?
A) Temperature
B) Pressure
C) Volume
D) Density

Answer: C Explanation: An extensive property is dependent on the amount of substance present in the system. Volume is an example of an extensive property as it increases with the amount of substance present.


Which of the following statements is true regarding the second law of thermodynamics?
A) Energy is conserved in all processes.
B) Energy flows from a higher temperature to a lower temperature.
C) The entropy of a system always increases.
D) The internal energy of a system is constant.

Answer: C Explanation: The second law of thermodynamics states that the entropy of an isolated system always increases or remains constant in a spontaneous process. It explains the direction of energy flow and the tendency towards greater disorder.

The standard entropy change (ΔS°) for a reaction is positive. What does it indicate about the reaction?
A) The reaction is spontaneous at all temperatures.
B) The reaction is non-spontaneous at all temperatures.
C) The reaction is spontaneous at high temperatures.
D) The reaction is spontaneous at low temperatures.

Answer: C Explanation: A positive ΔS° indicates that the disorder or randomness of the system increases during the reaction. While the reaction may not be spontaneous at all temperatures, it becomes spontaneous at higher temperatures where the increase in entropy overcomes the enthalpy factor.

Which of the following processes is exothermic?
A) Melting of ice
B) Sublimation of dry ice
C) Dissolution of ammonium nitrate in water
D) Formation of a metal oxide from its elements

Answer: D Explanation: An exothermic process releases heat energy to the surroundings. The formation of a metal oxide from its elements is usually an exothermic process as it involves the release of heat energy.

The standard Gibbs free energy change (ΔG°) for a reaction is negative. What does it indicate about the reaction?
A) The reaction is spontaneous at all temperatures.
B) The reaction is non-spontaneous at all temperatures.
C) The reaction is spontaneous at high temperatures.
D) The reaction is spontaneous at low temperatures.

Answer: A Explanation: A negative ΔG° indicates that the reaction is spontaneous under standard conditions. It means that the reaction will proceed in the forward direction without any external intervention.

Which of the following is a state function?
A) Heat
B) Work
C) Enthalpy
D) Temperature

Answer: C Explanation: A state function is a property that depends only on the current state of a system and is independent of the path taken to reach that state. Enthalpy is a state function, while heat and work are not.

Which of the following equations represents the first law of thermodynamics?
A) ΔU = q + w
B) ΔG = ΔH – TΔS
C) ΔH = ΔE + PΔV
D) ΔS = qrev/T

Answer: A Explanation: The equation ΔU = q + w represents the first law of thermodynamics, where ΔU is the change in internal energy, q is the heat transferred to the system, and w is the work done by the system.

Which of the following processes is spontaneous at all temperatures?
A) Freezing of water
B) Vaporization of water
C) Condensation of water vapor
D) Sublimation of ice

Answer: C Explanation: The condensation of water vapor is spontaneous at all temperatures because it involves the release of heat energy to the surroundings, leading to a decrease in entropy.

The entropy change (ΔS) for a reversible process is:
A) Always positive
B) Always negative
C) Zero
D) Can be positive, negative, or zero depending on the process

Answer: C Explanation: The entropy change (ΔS) for a reversible process is zero because a reversible process is characterized by no net change in entropy as it can be reversed without leaving any impact on the surroundings.

The value of ΔG for a spontaneous process is:
A) Always positive
B) Always negative
C) Zero
D) Can be positive, negative, or zero depending on the process

Answer: B Explanation: The value of ΔG (Gibbs free energy change) for a spontaneous process is always negative, indicating that the process will proceed in the forward direction without any external intervention.

Which of the following statements is true regarding an isothermal process?
A) The temperature of the system remains constant.
B) The pressure of the system remains constant.
C) The volume of the system remains constant.
D) The internal energy of the system remains constant.

Answer: A Explanation: In an isothermal process, the temperature of the system remains constant. It can involve changes in other properties such as pressure, volume, or internal energy.


Which of the following statements is true regarding the concept of entropy?
A) Entropy of a system always decreases in a spontaneous process.
B) Entropy of a system always increases in a spontaneous process.
C) Entropy of a system remains constant in a spontaneous process.
D) Entropy of a system is unrelated to spontaneity.

Answer: B Explanation: The concept of entropy states that the entropy of a system always increases in a spontaneous process, indicating a tendency towards greater disorder and randomness.

Which of the following factors affect the magnitude of entropy change in a process?
A) Temperature and pressure
B) Enthalpy and entropy
C) Volume and moles of substances involved
D) Heat and work

Answer: C Explanation: The magnitude of entropy change in a process depends on factors such as volume and the number of moles of substances involved. The increase in volume or the presence of more particles generally leads to a higher entropy change.

The standard Gibbs free energy change (ΔG°) for a reaction can be determined using:
A) Hess’s law
B) Kirchhoff’s law
C) Le Chatelier’s principle
D) Thermodynamic tables

Answer: D Explanation: The standard Gibbs free energy change (ΔG°) for a reaction can be determined using thermodynamic tables or data that provide the standard free energy values of individual substances involved in the reaction.

The change in enthalpy (ΔH) of a reaction is positive. What does it indicate about the reaction?
A) The reaction is exothermic.
B) The reaction is endothermic.
C) The reaction is spontaneous.
D) The reaction is non-spontaneous.

Answer: B Explanation: A positive change in enthalpy (ΔH) indicates that the reaction is endothermic, meaning it requires the input of heat energy from the surroundings.

Which of the following processes is characterized by a decrease in both enthalpy and entropy?
A) Sublimation
B) Melting
C) Freezing
D) Condensation

Answer: C Explanation: Freezing is characterized by a decrease in both enthalpy and entropy. The conversion of a substance from a liquid to a solid results in a decrease in both the energy and the disorder of the system.

Which of the following statements is true regarding spontaneous processes?
A) Spontaneous processes are always fast.
B) Spontaneous processes always lead to an increase in disorder.
C) Spontaneous processes can be reversed under any conditions.
D) Spontaneous processes do not require an input of energy.

Answer: D Explanation: Spontaneous processes occur naturally without an input of external energy. They can be fast or slow, and they can lead to an increase or decrease in disorder depending on the specific process.

The Clausius statement of the second law of thermodynamics relates to:
A) Energy conservation
B) Entropy increase
C) Heat flow from a higher to a lower temperature
D) Reversibility of processes

Answer: B Explanation: The Clausius statement of the second law of thermodynamics states that the entropy of an isolated system never decreases; it either remains constant or increases in a spontaneous process.

The standard enthalpy change (ΔH°) for a reaction is negative. What does it indicate about the reaction?
A) The reaction is exothermic.
B) The reaction is endothermic.
C) The reaction is spontaneous.
D) The reaction is non-spontaneous.

Answer: A Explanation: A negative standard enthalpy change (ΔH°) indicates that the reaction is exothermic, meaning it releases heat energy to the surroundings.

The change in internal energy (ΔU) of a system is given by:
A) ΔU = q + w
B) ΔU = ΔH – TΔS
C) ΔU = q
D) ΔU = w

Answer: C Explanation: The change in internal energy (ΔU) of a system is given by the heat transfer (q) to the system.

Which of the following factors affect the spontaneity of a process?
A) Enthalpy and entropy
B) Temperature and pressure
C) Volume and moles of substances involved
D) Heat and work

Answer: A Explanation: The spontaneity of a process is determined by the factors of enthalpy and entropy. A favorable change in both enthalpy and entropy leads to a spontaneous process.

We hope there JEE MCQ of Class 11 Thermodynamics will help you to score an excellent rank in JEE Mains and Advanced. If you have any queries feel free to write in the comments section. We at Study Rate are always ready to serve our students.

Sneha

Master's in Biology, Skilled in vocational training. Strong Analytical and creative knowledge.

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