50+ JEE Mains MCQ Questions Organic Chemistry: Basic Principles & Techniques with Solutions

Preparing for the Joint Entrance Exam (JEE) can be a daunting task. With so many subjects to cover and so many topics to study, it can be challenging to know where to start. One essential topic in the JEE Mains syllabus is the Organic Chemistry: Basic Principles & Techniques. In this article, we will provide 50+ MCQ questions on the Organic Chemistry: Basic Principles & Techniques, along with detailed solutions to help you prepare for the JEE Mains exam.

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These 50+ MCQ questions are selected by the experts of studyrate.in and these are more difficult questions, which will help you to better understand Organic Chemistry: Basic Principles & Techniques JEE Mains MCQ Questions with Answers.

Organic Chemistry: Basic Principles & Techniques JEE Mains MCQ

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH(CH3)CH2CH3
a) 3-methylhexane
b) 2,2-dimethylpentane
c) 2,4-dimethylpentane
d) 2,3-dimethylbutane

Answer: c) 2,4-dimethylpentane Explanation: The compound has a branched structure with two methyl groups on the second and fourth carbon atoms of the pentane chain.

What is the major product formed when butan-2-ol undergoes dehydration in the presence of concentrated sulfuric acid?
a) But-1-ene
b) But-2-ene
c) 2-methylpropene
d) Ethene

Answer: b) But-2-ene Explanation: Dehydration of butan-2-ol leads to the formation of but-2-ene as the major product.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2COOH
a) Ethanoic acid
b) Acetic acid
c) Propanoic acid
d) Butanoic acid

Answer: b) Acetic acid Explanation: The compound is a two-carbon carboxylic acid and its common name is acetic acid.

Which of the following compounds is an example of a secondary alcohol?
a) Methanol
b) Ethanol
c) Propanol
d) Butanol

Answer: c) Propanol Explanation: Propanol is a three-carbon alcohol with the hydroxyl (-OH) group attached to a secondary carbon.

Which of the following reagents is used for the oxidation of primary alcohols to aldehydes?
a) KMnO4
b) H2SO4
c) PCC
d) NaOH

Answer: c) PCC (pyridinium chlorochromate) Explanation: PCC is a mild oxidizing agent that selectively converts primary alcohols to aldehydes without further oxidation to carboxylic acids.

What is the major product formed when ethylbenzene undergoes catalytic hydrogenation?
a) Ethane
b) Benzene
c) Toluene
d) Cyclohexane

Answer: c) Toluene Explanation: Catalytic hydrogenation of ethylbenzene leads to the formation of toluene, with the double bond in ethylbenzene being reduced.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH(Cl)CH2CH(CH3)2
a) 3-chloro-2,3-dimethylbutane
b) 2-chloro-3,3-dimethylbutane
c) 2-chloro-2,3-dimethylbutane
d) 2-chloro-2,2-dimethylbutane

Answer: d) 2-chloro-2,2-dimethylbutane Explanation: The compound has a branched structure with a chlorine atom attached to the second carbon atom and two methyl groups on the second carbon atom.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH2CHO
a) Butanal
b) Butanone
c) Butanoic acid
d) Butanol
.

Answer: a) Butanal Explanation: The compound is a four-carbon aldehyde, and its IUPAC name is butanal

Which of the following is not a primary method of purification of organic compounds?
a) Distillation
b) Filtration
c) Crystallization
d) Chromatography

Answer: b) Filtration Explanation: Filtration is used to separate solid impurities from a liquid or a mixture, but it is not a primary method of purification for organic compounds.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH(CH3)CH2CH(CH3)CH2CH(CH3)2
a) 3,3-dimethylheptane
b) 2,5-dimethylhexane
c) 2,5,5-trimethylhexane
d) 3,4,4-trimethylheptane

Answer: c) 2,5,5-trimethylhexane Explanation: The compound has a branched structure with three methyl groups attached to the second and fifth carbon atoms of the hexane chain.

Which of the following techniques is commonly used to separate and purify organic compounds based on their boiling points?
a) Chromatography
b) Distillation
c) Filtration
d) Crystallization

Answer: b) Distillation Explanation: Distillation is a technique used to separate and purify organic compounds based on differences in their boiling points.

Which of the following reagents is used for the conversion of alkynes to cis-alkenes?
a) NaBH4
b) H2SO4
c) Lindlar catalyst
d) PBr3

Answer: c) Lindlar catalyst Explanation: The Lindlar catalyst, which is palladium on calcium carbonate modified with lead acetate, is used for the selective reduction of alkynes to cis-alkenes.

What is the major product formed when propanoic acid undergoes decarboxylation?
a) Propane
b) Propanal
c) Ethane
d) Ethanol

Answer: a) Propane Explanation: Decarboxylation of propanoic acid leads to the loss of the carboxyl group (-COOH) and the formation of propane.

Which of the following reagents is used for the conversion of primary alcohols to alkyl halides?
a) PCC
b) KMnO4
c) SOCl2
d) NaOH

Answer: c) SOCl2 (thionyl chloride) Explanation: Thionyl chloride is commonly used for the conversion of primary alcohols to alkyl halides through an SN2 reaction.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH(CH3)CH2CHO
a) Pentanal
b) 2-pentanone
c) 3-pentanone
d) 3-methylbutanal

Answer: d) 3-methylbutanal Explanation: The compound has a branched structure with a formyl (-CHO) group attached to the third carbon atom and a methyl group on the second carbon atom.

What is the major product formed when methylbenzene undergoes nitration with a mixture of concentrated nitric acid and concentrated sulfuric acid?
a) Toluene
b) Nitrotoluene
c) Benzene
d) Phenol

Answer: b) Nitrotoluene Explanation: Nitration of methylbenzene leads to the substitution of a nitro (-NO2) group on the benzene ring, forming nitrotoluene.

Which of the following techniques is commonly used to separate and purify organic compounds based on differences in their solubility in a mobile phase and a stationary phase?
a) Chromatography
b) Distillation
c) Filtration
d) Crystallization

Answer: a) Chromatography Explanation: Chromatography is a technique that utilizes the differential solubility of compounds in a mobile phase and a stationary phase to separate and purify organic compounds.

What is the major product formed when ethanal undergoes reduction in the presence of NaBH4?
a) Ethanol
b) Ethene
c) Propanal
d) Propane

Answer: a) Ethanol Explanation: Reduction of ethanal with NaBH4 leads to the formation of ethanol.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH2COCH3
a) Butanone
b) Propanal
c) Pentan-2-one
d) Butanoic acid

Answer: a) Butanone Explanation: The compound is a four-carbon ketone, and its IUPAC name is butanone.

Which of the following reagents is used for the conversion of aldehydes to primary alcohols?
a) LiAlH4
b) H2SO4
c) NaOH
d) PCC

Answer: a) LiAlH4 (lithium aluminum hydride) Explanation: LiAlH4 is a strong reducing agent used for the conversion of aldehydes to primary alcohols.

What is the major product formed when ethene undergoes bromination?
a) Ethane
b) 1,2-dibromoethane
c) 1,1-dibromoethane
d) 1-bromoethene

Answer: b) 1,2-dibromoethane Explanation: Bromination of ethene leads to the addition of two bromine atoms, resulting in the formation of 1,2-dibromoethane.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH(CH3)2
a) 2,2-dimethylbutane
b) 2-methylpentane
c) 3-methylpentane
d) 2,3-dimethylbutane

Answer: a) 2,2-dimethylbutane Explanation: The compound has a branched structure with two methyl groups attached to the second carbon atom.

Which of the following techniques is commonly used to separate and purify organic compounds based on their different rates of migration on a solid stationary phase?
a) Chromatography
b) Distillation
c) Filtration
d) Crystallization

Answer: a) Chromatography Explanation: Chromatography, particularly column chromatography or thin-layer chromatography, is used to separate compounds based on their different rates of migration on a solid stationary phase.

What is the major product formed when ethanol undergoes oxidation in the presence of acidified potassium dichromate (K2Cr2O7)?
a) Ethane
b) Ethene
c) Ethanal
d) Ethanoic acid

Answer: d) Ethanoic acid Explanation: Oxidation of ethanol with acidified potassium dichromate leads to the formation of ethanoic acid.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2CH2NH2
a) Ethanamine
b) Ethylamine
c) Butanamine
d) Propanamine

Answer: b) Ethylamine Explanation: The compound is a three-carbon amine, and its IUPAC name is ethylamine.

What is the major product formed when ethene reacts with hydrogen bromide (HBr)?
a) Ethane
b) 1-bromoethene
c) 2-bromoethene
d) 1,2-dibromoethane

Answer: b) 1-bromoethene Explanation: The reaction between ethene and HBr leads to the addition of a bromine atom, forming 1-bromoethene.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2COCH2CH3
a) 2-butanone
b) Butanoic acid
c) Ethyl methyl ketone
d) Propionic acid

Answer: c) Ethyl methyl ketone Explanation: The compound is a four-carbon ketone, and its common name is ethyl methyl ketone.

Which of the following reagents is used for the conversion of alkyl halides to alcohols?
a) PCC
b) NaOH
c) LiAlH4
d) H2SO4

Answer: b) NaOH Explanation: NaOH is used for the conversion of alkyl halides to alcohols through an SN2 reaction.

What is the major product formed when ethene reacts with chlorine (Cl2)?
a) Ethane
b) 1,2-dichloroethane
c) 1,1-dichloroethane
d) 1-chloroethene

Answer: b) 1,2-dichloroethane Explanation: The reaction between ethene and chlorine leads to the addition of two chlorine atoms, forming 1,2-dichloroethane.

Which of the following is the correct IUPAC name for the compound shown below?
CH3CH2COOCH2CH3
a) Ethyl ethanoate
b) Ethyl butanoate
c) Butyl ethanoate
d) Butyl butanoate

Answer: a) Ethyl ethanoate Explanation: The compound is an ester formed from ethanoic acid and ethanol, and its IUPAC name is ethyl ethanoate.

We hope there JEE MCQ of Class 11 Organic Chemistry: Basic Principles & Techniques will help you to score an excellent rank in JEE Mains and Advanced. If you have any queries feel free to write in the comments section. We at Study Rate are always ready to serve our students.

Sneha

Master's in Biology, Skilled in vocational training. Strong Analytical and creative knowledge.

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