50+ JEE Mains MCQ Questions Electrochemistry with Solutions

Preparing for the Joint Entrance Exam (JEE) can be a daunting task. With so many subjects to cover and so many topics to study, it can be challenging to know where to start. One essential topic in the JEE Mains syllabus is the Electrochemistry. In this article, we will provide 50+ MCQ questions on the Electrochemistry, along with detailed solutions to help you prepare for the JEE Mains exam.

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These 50+ MCQ questions are selected by the experts of studyrate.in and these are more difficult questions, which will help you to better understand Electrochemistry JEE Mains MCQ Questions with Answers.

Electrochemistry JEE Mains MCQ


Which of the following is not a redox reaction?
a) 2NaCl → 2Na + Cl2
b) Zn + CuSO4 → ZnSO4 + Cu
c) 2H2O → 2H2 + O2
d) 2HCl + Na2CO3 → 2NaCl + H2O + CO2

Answer: c) 2H2O → 2H2 + O2 Explanation: This reaction represents a decomposition reaction, not a redox reaction. In a redox reaction, there must be a transfer of electrons.

The standard electrode potential (E°) of a half-cell is a measure of:
a) Ion concentration in the half-cell
b) Current flowing through the half-cell
c) Cell potential of the galvanic cell
d) Reduction potential of the electrode

Answer: d) Reduction potential of the electrode Explanation: The standard electrode potential (E°) of a half-cell represents the reduction potential of the electrode relative to the standard hydrogen electrode (SHE).

Which of the following statements about the Nernst equation is correct?
a) It relates the concentration of reactants to the equilibrium constant.
b) It determines the standard electrode potential of a half-cell.
c) It calculates the pH of a solution.
d) It relates the electrode potential to the concentration of reactants and products.

Answer: d) It relates the electrode potential to the concentration of reactants and products. Explanation: The Nernst equation relates the electrode potential of a half-cell to the concentrations of reactants and products involved in the electrode reaction.

In the electrolysis of water, hydrogen gas is evolved at the:
a) Cathode and anode
b) Cathode only
c) Anode only
d) Neither cathode nor anode

Answer: b) Cathode only Explanation: In the electrolysis of water, hydrogen gas (H2) is evolved at the cathode, while oxygen gas (O2) is evolved at the anode.

The Faraday constant (F) represents the charge carried by:
a) One mole of electrons
b) One mole of protons
c) One mole of ions
d) One mole of any particle

Answer: a) One mole of electrons Explanation: The Faraday constant (F) represents the charge carried by one mole of electrons. Its value is approximately 96,485 C/mol.

Which of the following substances acts as an oxidizing agent?
a) Na
b) Fe
c) Cl2
d) H2

Answer: c) Cl2 Explanation: Chlorine gas (Cl2) acts as an oxidizing agent because it can accept electrons and undergo reduction in a redox reaction.

The cell potential (Ecell) of a galvanic cell can be calculated using the equation:
a) Ecell = E°cathode – E°anode
b) Ecell = E°anode – E°cathode
c) Ecell = E°cathode + E°anode
d) Ecell = E°anode + E°cathode

Answer: b) Ecell = E°anode – E°cathode Explanation: The cell potential (Ecell) of a galvanic cell can be calculated by subtracting the standard electrode potential (E°) of the anode from the standard electrode potential of the cathode.

Which of the following is the correct representation of a cell notation?
a) Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s)
b) Ag(s) | Ag+(aq) || Cu2+(aq) | Cu(s)
c) Cu2+(aq) | Cu(s) || Ag(s) | Ag+(aq)
d) Ag+(aq) | Ag(s) || Cu(s) | Cu2+(aq)

Answer: a) Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s) Explanation: The cell notation represents the anode on the left side and the cathode on the right side, separated by double vertical lines. The solid electrode is written on the left, followed by the corresponding aqueous ion.

Which of the following statements about the salt bridge in a galvanic cell is correct?
a) It allows the flow of electrons between the electrodes.
b) It completes the circuit and maintains electrical neutrality in the half-cells.
c) It prevents the migration of ions in the solution.
d) It provides a barrier to the flow of current.

Answer: b) It completes the circuit and maintains electrical neutrality in the half-cells. Explanation: The salt bridge in a galvanic cell completes the circuit by allowing the flow of ions between the half-cells. It maintains electrical neutrality by balancing the charges in the half-cells.

The efficiency of an electrolytic cell is given by the ratio:
a) Amount of product obtained / Amount of reactant consumed
b) Amount of product obtained / Theoretical amount of product
c) Amount of reactant consumed / Amount of product obtained
d) Theoretical amount of product / Amount of product obtained

Answer: b) Amount of product obtained / Theoretical amount of product Explanation: The efficiency of an electrolytic cell is given by the ratio of the actual amount of product obtained to the theoretical amount of product calculated from Faraday’s laws.

Which of the following is not a common reference electrode?
a) Standard hydrogen electrode (SHE)
b) Silver/silver chloride electrode (Ag/AgCl)
c) Calomel electrode (Hg2Cl2/Hg)
d) Platinum electrode (Pt)

Answer: d) Platinum electrode (Pt) Explanation: Platinum electrode (Pt) is not a reference electrode. It is commonly used as an inert electrode to conduct the current in the cell.

The electrode potential of the standard hydrogen electrode (SHE) is defined as:
a) 0 V
b) +1 V
c) -1 V
d) +0.059 V

Answer: a) 0 V Explanation: The electrode potential of the standard hydrogen electrode (SHE) is defined as 0 V. It serves as the reference point for measuring the electrode potentials of other half-cells.

The process of the movement of cations towards the cathode in an electrolytic cell is called:
a) Reduction
b) Oxidation
c) Discharge
d) Migration

Answer: d) Migration Explanation: Migration refers to the movement of ions towards the respective electrodes in an electrolytic cell. In this case, cations move towards the cathode, while anions move towards the anode.

The process of the conversion of an element into its corresponding cation during a redox reaction is called:
a) Reduction
b) Oxidation
c) Discharge
d) Reduction potential

Answer: b) Oxidation Explanation: Oxidation refers to the process in which an element loses electrons and is converted into its corresponding cation during a redox reaction.

The standard electrode potential of a half-cell represents the:
a) Ability of the electrode to gain electrons
b) Ability of the electrode to lose electrons
c) Ability of the electrode to attract cations
d) Ability of the electrode to attract anions

Answer: b) Ability of the electrode to lose electrons Explanation: The standard electrode potential of a half-cell represents the ability of the electrode to lose electrons and undergo reduction compared to the standard hydrogen electrode (SHE).

Which of the following substances acts as a reducing agent?
a) Ag+
b) Cl-
c) H2O
d) Na+

Answer: d) Na+ Explanation: Sodium ion (Na+) acts as a reducing agent because it has the tendency to lose electrons and undergo oxidation in a redox reaction.

Which of the following factors does not affect the cell potential (Ecell) of a galvanic cell?
a) Concentration of reactants and products
b) Temperature
c) Pressure
d) Nature of the electrodes and their surfaces

Answer: c) Pressure Explanation: Pressure does not directly affect the cell potential (Ecell) of a galvanic cell. The other factors mentioned can influence the cell potential.

The balancing of redox reactions in acidic medium involves the addition of:
a) H2O molecules
b) OH- ions
c) H+ ions
d) e- (electrons)

Answer: c) H+ ions Explanation: Balancing redox reactions in acidic medium involves the addition of H+ ions to balance the total charges and maintain electrical neutrality.

Which of the following is true about a concentration cell?
a) The electrodes are made of different materials.
b) The cell potential is independent of the concentration of the electrolyte.
c) The cell potential is zero when the concentrations of the electrolyte are equal.
d) The cell potential is positive when the cathode concentration is higher than the anode concentration.

Answer: c) The cell potential is zero when the concentrations of the electrolyte are equal. Explanation: In a concentration cell, the cell potential is zero when the concentrations of the electrolyte in both half-cells are equal. The cell potential becomes nonzero when there is a concentration difference between the two half-cells.

The process of depositing a layer of metal on another metal surface by electrolysis is called:
a) Electrolysis
b) Electroplating
c) Electrodeposition
d) Electrophoresis

Answer: b) Electroplating Explanation: Electroplating refers to the process of depositing a layer of metal on another metal surface by electrolysis. It is commonly used for coating objects with a thin layer of metal for various purposes.

Which of the following statements about corrosion is correct?
a) Corrosion is a reduction process.
b) Corrosion only occurs in the presence of air.
c) Corrosion can be prevented by using a metal with a lower reduction potential.
d) Corrosion is a reversible process.

Answer: a) Corrosion is a reduction process.


In the reaction: 2HCl(aq) + 2e- → H2(g) + 2Cl-(aq), the reducing agent is:
a) HCl(aq)
b) H2(g)
c) Cl-(aq)
d) e-

Answer: a) HCl(aq) Explanation: The reducing agent is the species that undergoes oxidation. In this reaction, HCl is oxidized to form H2, so HCl is the reducing agent.

Which of the following species is reduced in the reaction: Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)?
a) Zn(s)
b) Cu2+(aq)
c) Zn2+(aq)
d) Cu(s)

Answer: b) Cu2+(aq) Explanation: Cu2+(aq) is reduced to Cu(s) by gaining electrons. It undergoes a reduction half-reaction.

The standard reduction potential (E°) of a half-cell reaction is a measure of:
a) The rate of the reaction
b) The stoichiometry of the reaction
c) The electrode potential of the half-cell
d) The equilibrium constant of the reaction

Answer: c) The electrode potential of the half-cell Explanation: The standard reduction potential (E°) of a half-cell reaction represents the tendency of a species to gain electrons at the standard state. It is a measure of the electrode potential of the half-cell

.

In a galvanic cell, which electrode is the cathode?
a) The electrode with the higher reduction potential
b) The electrode with the lower reduction potential
c) The electrode where oxidation occurs
d) The electrode where reduction occurs

Answer: a) The electrode with the higher reduction potential Explanation: In a galvanic cell, the cathode is the electrode where reduction occurs. Reduction takes place at the electrode with the higher reduction potential.

The cell potential of a galvanic cell is calculated as:
a) The sum of the reduction potentials of the two half-cells
b) The difference between the reduction potentials of the two half-cells
c) The sum of the oxidation potentials of the two half-cells
d) The difference between the oxidation potentials of the two half-cells

Answer: b) The difference between the reduction potentials of the two half-cells Explanation: The cell potential (Ecell) of a galvanic cell is calculated by taking the difference between the reduction potentials (E°red) of the two half-cells: Ecell = E°red(cathode) – E°red(anode).

The Nernst equation relates the cell potential (Ecell) to the concentrations of reactants and products. It is given by:
a) Ecell = E°cell – (RT/nF) ln(Q)
b) Ecell = E°cell + (RT/nF) ln(Q)
c) Ecell = E°cell – (nF/RT) ln(Q)
d) Ecell = E°cell + (nF/RT) ln(Q)

Answer: b) Ecell = E°cell + (RT/nF) ln(Q) Explanation: The Nernst equation relates the cell potential (Ecell) to the concentrations of reactants and products. It is given by Ecell = E°cell + (RT/nF) ln(Q), where R is the gas constant, T is the temperature, n is the number of electrons transferred, F is the Faraday constant, and Q is the reaction quotient.

The standard hydrogen electrode (SHE) is used as a reference electrode because:
a) It has a very high reduction potential
b) It is inert and does not participate in the redox reaction
c) It is easy to prepare and maintain
d) It has a constant temperature

Answer: b) It is inert and does not participate in the redox reaction Explanation: The standard hydrogen electrode (SHE) is used as a reference electrode because it is inert and does not participate in the redox reaction. It provides a standard against which other electrode potentials can be measured.

The Faraday constant (F) represents the charge carried by:
a) One mole of electrons
b) One mole of protons
c) One mole of ions
d) One mole of neutrons

Answer: a) One mole of electrons Explanation: The Faraday constant (F) represents the charge carried by one mole of electrons. It is equal to 96,485 C/mol.

The number of electrons transferred in the following reaction: MnO4-(aq) + 8H+(aq) + 5e- → Mn2+(aq) + 4H2O(l) is:
a) 1
b) 2
c) 3
d) 5

Answer: d) 5 Explanation: In the balanced half-reaction, 5 electrons are transferred from the reactants to the products.

Which of the following statements about concentration cells is correct?
a) They do not involve any redox reactions.
b) The cell potential is always zero.
c) They utilize a concentration gradient as the driving force.
d) The electrode potential does not depend on the concentration of species.

Answer: c) They utilize a concentration gradient as the driving force. Explanation: Concentration cells utilize a concentration gradient as the driving force for the flow of electrons. The cell potential arises due to the difference in concentrations between the two half-cells.

We hope there JEE MCQ of Class 12 : Electrochemistry will help you to score an excellent rank in JEE Mains and Advanced. If you have any queries feel free to write in the comments section. We at Study Rate are always ready to serve our students.

Sneha

Master's in Biology, Skilled in vocational training. Strong Analytical and creative knowledge.

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